Novel halogermanides and methods for the preparation thereof

ABSTRACT

A trichlorogermanide of formula (I): [R4N]/[R4P]Cl[GeCl3] (I), where R is Me, Et, iPr, nBu, or Ph, tris(trichlorosilyl)germanide of formula (II): [R4N]/[R4P][Ge(SiCl3)3] (II), where R is Me, Et, iPr, nBu, or Ph, a tris(trichlorosilyl)germanide adduct of GaCl3 of formula (III): [Ph4P][Ge(SiCl3)3*GaCl3], and a tris(trichlorosilyl)germanide adduct of BBr3 of formula (IV): [Ph4P][Ge(SiCl3)3*BBr3]. Also, methods for preparing the trichlorogermanides of formula (I), the tris(trichlorosilyl)germanide of formula (II), the tris(trichlorosilyl)germanide adduct of BBr3 of formula (IV).

CROSS-REFERENCE TO RELATED APPLICATIONS

The present application claims priority to EP Application No. 17173959.2, filed on Jun. 1, 2017, the entire contents of each of which are hereby incorporated by reference.

STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH OR DEVELOPMENT

Not applicable.

THE NAMES OF THE PARTIES TO A JOINT RESEARCH AGREEMENT

Not applicable.

INCORPORATION-BY-REFERENCE OF MATERIAL SUBMITTED ON A COMPACT DISC

Not applicable.

BACKGROUND OF THE INVENTION Field of the Invention

The present invention relates to novel halogermanides and a method for the preparation thereof.

Description of the Related Art

Halosilanes, polyhalosilanes, halogermanes, polyhalogermanes, silane, polysilanes, germane, polygermanes and corresponding mixed compounds have long been known, cf., in addition to the customary text books of inorganic chemistry, also WO 2004/036631 A2 or C. J. Ritter et al., J. Am. Chem. Soc., 2005, 127, 9855-9864.

L. Muller et al. in J. Organomet. Chem., 1999, 579, 156-163 describe, inter alia, the preparation of trichlorosilylmethylgermanes.

Methylgermylsilanes and phenylgermylsilanes are known from Angew. Chem., 1993, 105, 587-588 (G. Sih et al.) and also from Tetrahedron Lett., 1970, 51, 4443-4447 (F. Feher et al.).

Furthermore, phenyl- and hydrogen-containing compounds are known in which Sn—Si and Sn—Ge bonds are present (J. B. Tice et al J. Inorganic Chemistry, 2009, 48(13), 6314-6320). Here, it is suggested to use these compounds as IR semiconductors.

In patent document U.S. Pat. No. 7,540,920 B2, Singh et al. disclose Si—Ge compounds of the formula X₁X₂X₃—Si—Ge—X₄X₅X₆ having hydrogen or halogen radicals X₁₋₆.

BRIEF SUMMARY OF THE INVENTION

Practically nothing is currently known about chlorosilylarylgermanes. Thus, by means of basic research, effort is being made to find novel compounds and to seek novel preparation routes, in particular also with respect to potential industrial and optionally improvable applications.

The object of the present invention is to provide novel germanium and silicon-germanium compounds and also a method for the preparation thereof.

New synthetic possibilities for preparing silicon-germanium compounds, particularly

R₃Ge—SiCl₃, Cl₃Si—GeR₂—GeR₂—SiCl₃, Cl₃Ge—SiCl₃, [Ph₄P][Ge(SiCl₃)₃],

[Ph₄P][Ge(SiCl₃)₃*GaCl₃], [Ph₄P][Ge(SiCl₃)₃*BBr₃], by the reaction of chlorinated or perchlorinated, organic or inorganic germanium compounds of the type R_(n),GeCl_(4-n) (n=0,2,3) with hexachlorodisilane with addition of catalytic amounts of an ammonium chloride salt [R₄N]Cl where the radicals R=Me, Et, iPr, nBu were presented in the patent applications entitled “Neve Chlorsilylarylgermane, Verfahren zu deren Herstellung und deren Verwendung” (Novel chlorosilylarylgermanes, methods for preparation thereof and use thereof) and “Triphenylgermylsilan, Verfahren zur Herstellung und seine Verwendung” (Triphenylgermylsilane, method of preparation and its use). By means of the reaction, various silicon-germanium compounds are obtained.

In addition, it has been found that reactants of the type R₃GeCl are converted by the reaction with Si₂Cl₆ in the presence of ammonium chloride, whereupon a Ge—Si bond is formed at the Ge—Cl position. In the reaction of R₂GeCl₂ with Si₂Cl₆/ammonium chloride, the Ge—Si bond formation takes place at only one Ge—Cl position. In addition, Ge—Ge bond formation occurs at the second Ge—Cl position. The germanium-silicon compound thus found or prepared can be converted with LiAlH₄ to silicon hydride compounds. In the context of the invention, such compounds are prepared by the synthesis of Ph₃Ge—SiH₃ from Ph₃Ge—SiCl₃ for example. In the case of reactions of compounds of the type R_(n)GeCl_(4-n) (n=0), different reactions take place depending on the stoichiometry.

[R₄N][GeCl₃] salts (GeCl₄:Si₂Cl₆:[R₄N]Cl, 1:1:1),

Cl₃Si—GeCl₃ (GeCl₄:Si₂Cl₆:[R₄N]Cl, 1:1:0.1), or

[Ph₄P][Ge(SiCl₃)₃](GeCl₄: Si₂Cl₆: [Ph₄P]Cl, 1:4:1) were produced. [Ph₄P][Ge(SiCl₃)₃] can be reacted with Lewis acids, abbreviated to “LA”, to give the corresponding adducts [Ph₄P][Ge(SiCl₃)₃*LA].

BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS

A more complete appreciation of the invention and many of the attendant advantages thereof will be readily obtained as the same becomes better understood by reference to the following detailed description when considered in connection with the accompanying drawings, wherein:

FIG. 1A: Crystal Structure of trichlorosilyltriphenylgermane (1).

FIG. 1B: ²⁹Si-NMR spectrum of the crude product of the synthesis of trichlorosilyltriphenylgennane (1).

FIG. 2: Crystal Structure of 1,2-bis(trichlorosilyl)-1,1,2,2-tetraphenyldigermane (2).

FIG. 3: ²⁹ Si-NMR spectrum of trichlorosilyltrichlorogennane (3).

FIG. 4: Crystal structure of trichlorogennanide (4).

FIG. 5A: Crystal structure of tris(trichlorosilyl)germanide (5).

FIG. 5B: ²⁹Si-NMR spectrum of tris(trichlorosilyl)gennanide (5).

FIG. 6A: Crystal structure of tris(trichlorosilyl)germanide adduct of GaCl₃ (6).

FIG. 6B: ²⁹Si-NMR spectrum of tris(trichlorosilyl)germanide adduct of GaCl₃ (6).

FIG. 7A: Crystal structure of tris(trichlorosilyl)germanide adduct of BBr₃ (7).

FIG. 7B: ²⁹Si-NMR spectrum of tris(trichlorosilyl)germanide adduct of BBr₃ (7).

DETAILED DESCRIPTION OF THE INVENTION

In the context of the invention, the measure “equivalent”, “eq.” for short, is understood to mean the amount of catalyst in mol based on the amount of hexachlorodisilane in mol. For example, 0.1 eq of catalyst denotes 0.1 mol of catalyst per mole of hexachlorodisilane or 10 mol % of catalyst based on hexachlorodisilane.

In the context of the invention. “hexachlorodisilane” is also abbreviated to “HCDS”.

Chlorosilylarylgermanes are prepared by

(a) dissolving an arylchlorogermane with hexachlorodisilane in a solvent and

(b) reacting in the presence of a catalyst at a temperature of 5 to 40° C., wherein the aryl groups of the arylchlorogermane are each independently phenyl.

The chlorosilylarylgermanes can be selected from the series comprising trichlorosilyltriphenylgermane and/or 1,2-bis(trichlorosilyl)-1,1,2.2-tetraphenyldigermane.

Step (b) of said preparation method can be carried out at room temperature.

In step (a) of the method, a triarylchlorogermane may be used in a molar ratio to hexachlorodisilane of 1:1 and/or a diaryldichlorogermane may be used in a molar ratio to hexachlorodisilane of 1:2.

Furthermore, it is possible to use an arylchlorogermane from the series comprising triphenylchlorogermane and/or diphenyldichlorogermane

The solvent used in step (a) may be selected to be inert in order to avoid undesired reactions with HCDS. Furthermore, dichloromethane may be used since this does not react with HCDS in the chosen temperature ranges.

When carrying out the method according to the invention, phosphonium chlorides [R₄P]Cl or ammonium chloride salts [R₄N]Cl may be used as catalyst, where the radicals R are selected from Me, Et, iPr, nBu, Ph.

In this case, the reaction proceeds more slowly the less catalyst used. On the other hand, excessively large amounts of catalyst are undesirable since this has to be removed at the end of the reaction. The method can be carried out economically with respect to the separation complexity if the catalyst is used in an amount of 0.001 to 1 mol per mole of hexachlorodisilane. The method is carried out particularly favourably if 0.01 to 0.1 mol is used per mole of hexachlorodisilane.

A further aspect of carrying out the method economically is the selection of the amount of solvent. In the method, at least 5 mol of solvent can be used per mole of hexachlorodisilane, preferably 10 mol to 100 mol of solvent per mole of hexachlorodisilane.

In the method, the reaction may be carried out with thorough mixing, preferably with stirring, and over a period of 1 to 24 hours, preferably over the course of 12 h, and further preferably under protective gas, preferably under nitrogen or argon. The solvent can be subsequently removed. This can be undertaken preferably in a dry oxygen-free environment, particularly preferably in an isolated environment, for example in a glove box, and further preferably at standard pressure or under reduced pressure, preferably in the range of 1 to 500 hPa, wherein chlorosilylarylgermanes are obtained as crystalline product.

The trichlorosilyltrichlorogermane molecule of interest can also be prepared, which has already been disclosed by Singh et al. (U.S. Pat. No. 7,540,920 B2) without a method of preparation. For this purpose, GeCl₄ is used instead of the arylchlorogermane. The conversion reaction with hexachlorodisilane is then subsequently carried out in a solvent and in the presence of a catalyst.

In the preparation of trichlorosilyltrichlorogermane, GeCl₄ is dissolved with hexachlorodisilane in a solvent and the reaction is conducted in the presence of a catalyst at a temperature of 5 to 40° C.

It can be advantageous to use the catalyst in amounts of 0.001 to 1 eq., preferably 0.01 to 0.1 eq. Example 3 describes an exemplary procedure of this method.

if this method is further modified by using the ammonium chloride salt [R₄N]Cl or phosphonium chloride salts [R₄P]Cl in a stoichiometric amount instead of a catalytic amount, preferably from 0.5 to 1.5 eq., particularly preferably 1 eq., then halogermanides are surprisingly obtained, namely trichlorogermanide on using [R₄N]Cl.

The invention therefore provides trichlorogermanides of the general formula I

[R₄N]/[R₄P]Cl[GeCl₃], where R=Me, Et, iPr, nBu.tm (I)

In the context of the invention, “[R₄N]/[R₄P]Cl ” in the formula I is understood to mean that phosphonium or ammonium salts are obtained.

The invention also relates to a method for preparing trichlorogermanides (I) according to the invention, by dissolving GeCl₄ with hexachlorodisilane in a solvent and reacting in the presence of a stoichiometric amount of [R₄N]Cl or [R₄P]Cl at a temperature of 5 to 40° C.

Example 4 describes a preferred procedure where R=nBu.

The synthesis carried out according to Example 4 presents a novel possibility of obtaining [R₄N][GeCl₃] salts and [R₄P]Cl[GeCl₃] salts, by varying the cation [R₄N]⁺ or [R₄P]⁺ and by using the desired chloride salt for the heterolytic cleavage of Si₂Cl₆. This is particularly interesting since it has been found that the cation determines how well a compound crystallizes.

For instance, a large variety of [R₄N][GeCl₃] salts and [R₄P]Cl[GeCl₃] salts can be prepared in accordance with the invention.

If, in a modification of the method, the starting materials Si₂Cl₆ and GeCl₄ are used in a ratio of 4:1 with addition of stoichiometric amounts of [R₄N]Cl or [R₄P]Cl, trisnrichlorosilyl)germanide is surprisingly obtained.

For example, [Ph₄P]Cl can be used (Example 5).

The invention likewise provides tris(trichlorosilyl)germanide of the formula II,

[R₄P]/[R₄N][Ge(SiCl₃)₃].  (II)

The invention therefore likewise provides a method for preparing the tris(trichlorosilyl)germanide (II) according to the invention, by dissolving hexachlorodisilane with GeCl₄ in a solvent and reacting in the presence of a stoichiometric amount of [R₄N]Cl or [R₄P]Cl at a temperature of 5 to 40° C. A preferred ratio of hexachlorodisilane to GeCl₄ is 4:1.

The stoichiometric amount used is preferably from 0.5 to 1.5 eq., particularly preferably 1 eq. of [R₄N]Cl or [R₄P]Cl. An illustrative synthesis of the germanide (II) according to the invention is more particularly elucidated in Example 5.

If the tris(trichlorosilyl)germanide according to the invention or obtained according to the invention is reacted with GaCl₃, tris(trichlorosilyl)germanide adduct of GaCl₃ is obtained: [Ph₄P][Ge(SiCl₃)₃*GaCl₃].

The invention therefore likewise provides the adduct of the formula III,

[Ph₄P][Ge(SiCl₃)₃*GaCl₃],  (III)

and likewise the method for preparation thereof by mixing the tris(trichlorosilyl)germanide according to the invention or obtained according to the invention with GaCl₃ and dissolving the resulting mixture in dichloromethane with stirring, whereupon the adduct III is obtained at a temperature of 5 to 40° C. over a period of 1 to 24 hours.

A more detailed elucidation of the synthesis is specified in Example 6.

Instead of the reaction according to the invention of tris(trichlorosilyl)germanide with GaCl₃, tris(trichlorosilyl)germanide can be reacted with BBr₃. In this case, the tris(trichlorosilyl)germanide adduct of BBr₃ is found.

The invention therefore likewise provides the adduct of the formula IV,

[Ph₄P][Ge(SiCl₃)₃*BBr₃],  (IV)

and likewise the method for preparation thereof by mixing the tris(trichlorosilyl)germanide according to the invention or obtained according to the invention with BBr₃ and dissolving the resulting mixture in dichloromethane with stirring, whereupon the adduct IV is obtained at a temperature of 5 to 40° C. over a period of 1 to 120 hours.

A more detailed elucidation of this synthesis is specified in Example 7.

The Ge or Si—Ge compounds according to the invention or prepared in accordance with the invention may serve as precursors for materials which are used for the controlled deposition of thin Si—Ge layers.

The examples which follow provide additional illustration of the present invention without restricting the subject matter. The term “room temperature” is abbreviated to “RT” in the examples.

Analytical methods for determination of the crystal structure

The data for all structures were collected at 173 K using a STOE IPDS II dual beam diffractometer using a Genix microfocus tube with mirror optics using MoK_(α) radiation (λ=0.71073 Å) and scaled using the frame scaling procedure of the X-AREA program (Stoe & Cie, 2002). The structures were solved by direct methods with the aid of the SHELXS program (Sheldrick, 2008) and refined on F² by the full matrix least squares technique. Cell parameters were determined by refinement on θ values of the reflections with I>6σ(I).

Input materials:

Hexachlorodisilane, “HCDS” for short, GeCl₄ from Evonik Industries AG, triphenylchlorogermane, diphenyldichlorogermane.

Example 1: Preparation of trichlorosilyltriphenylgermane (1).

The synthesis was carried out according to Equation 1 from Ph₃GeCl and Si₂Cl₆ with addition of a catalytic amount of 0.1 eq of [nBu₄N]Cl.

To a clear colourless solution of 500 mg, corresponding to 1.47 mmol, of Ph₃GeCl and 40 mg or 0.14 mmol of [nBu₄N]Cl in 5 ml or 78.3 mmol of CH₂Cl₂ were added at room temperature while stirring 400 mg, corresponding to 1.49 mmol, of Si₂Cl₆. A clear colourless reaction solution was obtained which was stirred at room temperature over the course of 12 h. A crude product in the form of a colourless crystalline solid 1 could be isolated from the reaction solution after slow removal of the solvent. The yield was 59%. The crude product still comprised up to about 30% of the reactant Ph₃GeCl. By X-ray diffractometry, it was possible to determine the crystal structure of 1 (FIG. 1A). The unmarked atoms in the figure represent hydrogen.

The ²⁹Si-NMR spectrum of 1 is shown in FIG. 1B. All results of a ¹H, ¹³C and ²⁹Si NMR spectroscopic investigation:

²⁹Si-NMR (99.4 MHz, CD₂Cl₂, 298 K): δ=13.3.

¹H-NMR (500.2 MHz, CD₂Cl₂, 298 K): δ=7.58 (m); 7.75 (dd ³J(H,H)=8.0 Hz, ²J(H,H)=1.4 Hz).

¹³C-NMR (125.0 MHz, CD₂Cl₂, 298 K): δ=128.9; 130.1; 132.2; 135.3.

Example 2:

Preparation of 1,2-bis(trichlorosilyl)-1,1,2,2-tetraphenyldigermane (2).

The synthesis was carried out according to Equation 2 from Ph₇GeCl₂ and Si₂Cl₆ with addition of catalytic amounts (0.1 eq) of [nBu₄N]Cl.

To a clear colourless solution comprising 500 mg or 1.68 mmol of Ph₂GeCl₂ and 90 mg or 0.32 mmol of [nBu₄N]Cl in 5 ml or 78.3 mmol of CH₂Cl₂, Si₂Cl₆ was added at room temperature. The resulting reaction solution was subsequently stirred over the course of 12 h.

A crude product 2 could be obtained in a yield of 77% from the reaction solution after slow removal of the solvent which could be isolated by extraction with Et₂O and subsequent crystallization. The yield in this case was 57%. By X-ray diffractometry, it was possible to determine the crystal structure of 2, shown in FIG. 2.

All results of a ¹H, ¹³C and ²⁹Si NMR spectroscopic investigation:

²⁹Si-NMR (99.4 MHz, CD₂Cl₂, 298 K): δ=12.3

¹H-NMR (500.2 MHz, CH₂Cl₂, 298 K): δ=7.41 (t³J(H.H)=7.2 Hz (2H)), 7.47 (d³J(H,H)=7.2 Hz (1H)), 7.56 (d³J(H,H)=7.2 Hz (2H)).

¹³C-NMR (125.0 MHz, CH₂Cl₂, 298 K): δ=129.0; 130.1; 131.8; 136.0.

Example 3: Preparation of trichlorosilyltrichlorogermane (3).

The synthesis was effected according to Equation 3 from GeCl₄ and Si₂Cl₆ (1:1) with addition of 0.1 eq. of [nBu₄N]Cl as a catalytic amount.

To a clear colourless solution comprising 100 mg or 0.4 mmol of [nBu₄N]Cl in a 30:70 mixture of GeCl₄ and CH₂Cl₂ was added at room temperature 1 g or 3.7 mmol of Si₂Cl₆ and the reaction mixture thus obtained was stirred at room temperature over the course of 12 h.

The product 3 was condensed with other volatile constituents from the reaction solution into a nitrogen-cooled receiver. Subsequent distillation at 140° C. at 1013 hPa resulted in the isolation of pure 3 as a clear colourless liquid in a yield of 22%.

The ²⁹Si-NMR spectrum of 3 is shown in FIG. 3.

All results of a ²⁹Si-NMR spectroscopic investigation:

²⁹Si-NMR (99.4 MHz, CH₂Cl₂, 298 K): δ=−6.3.

Example 4: Preparation of trichlorogermanide (4).

To a clear colourless solution of 300 mg or 1.4 mmol of GeCl₄ and 390 mg or 1.4 mmol of [Bu₄N]Cl in CH₂Cl₂ were added at room temperature 375 mg or 1.4 mmol of Si₂Cl₆ and the reaction mixture thus obtained was stirred over the course of 12 h. Trichlorogermanide 4 could be isolated from the reaction solution as a yellow crystalline solid after slow removal of the solvent. By means of X-ray diffractometry, the structure of 4 could be determined, shown in FIG. 4. For reasons of clarity, the cation [nBu₄N]⁺ is not depicted here.

Example 5: Preparation of tris(trichlorosilyl)germanide (5).

The synthesis was effected according to Equation 5 from GeCl₄ and Si₂Cl₆ in a molar ratio of 1:4 with addition of a stoichiometric amount, in this case 1 eq., of [Ph₄P]Cl.

To a clear colourless solution comprising 93 rng or 0.4 mmol of GeCl₄ and 163 mg or 0.4 mmol of [Ph₄P]Cl in CH₂Cl₂ as solvent were added at room temperature 478 mg or 1.7 mmol of Si₂Cl₆ and the reaction mixture thus obtained was stirred over the course of 12 h. 5 could be isolated in 99% yield from this mixture as a yellow crystalline solid after slow removal of the solvent. By means of X-ray diffractometry, the crystal structure of 5 could be determined, shown in FIG. 5A. For reasons of clarity, the cation [Ph₄P]⁺ is not depicted here.

In this reaction there is a reduction of the GeCl₄. In addition, a three-fold silylation of the germanium atom takes place.

The ²⁹Si-NMR spectrum of 5 is shown in FIG. 5B.

All results of a ¹H- and ²⁹Si-NMR spectroscopic investigation:

²⁹Si-NMR (99.4 MHz; CD₂Cl₂; 298 K): δ=29.7.

¹H-NMR (500.2 MHz; CD₂Cl₂; 298 K): δ=7.54 (qd³J(H,H)=4.5 Hz;²J(H,H)=1.3 Hz; (2H)); 7.68 (td³J(H,H)=7.4 Hz; ³J(H,H)=3.4 Hz (2H)); 7.84 (tt³J(H,H)=7Hz; ²J(H,H)=1.0 Hz (1H)).

Example 6: Preparation of tris(trichlorosilyl)germanide adduct of GaCl₃ (6).

The synthesis of 6 was effected according to Equation 6 from tris(trichlorosilyl)germanide (5) and GaCl₃.

[Ph₄P][Ge(SiCl₃)₃]+GaCl₃

[Ph₄P][Ge(SiCl₃)₃*GaCI₃] Equation 6: Reaction of 5 with GaCl₃.

50 mg or 0.1 mmol of 5 and 10 mg or 0.1 mmol of GaCl₃ were mixed as solids at room temperature and subsequently dissolved completely in CH₂Cl₂. The clear yellow reaction mixture was stirred at room temperature over the course of 12 h. 6 could be obtained from the clear yellow reaction solution as a yellow crystalline solid in a yield of 82% after slow removal of the solvent.

By means of X-ray diffractometry, the crystal structure of 6 could be determined, shown in FIG. 6A. For reasons of clarity, the cation [Ph₄P]⁺ is not depicted here.

The ²⁹Si-NMR spectrum of 6 is shown in FIG. 6B.

All results of a ¹H- and ²⁹Si-NMR spectroscopic investigation:

²⁹Si-NMR (99.4 MHz, CD₂Cl₂, 298 K): δ=11.3.

¹H-NMR (500.2 MHz; CD₂Cl₂; 298 K): δ=7.54 (qd³J(H,H)=4.5 Hz; ²J(H,H)=1.3 Hz; (2H)); 7.68 (td³J(H,H)=7.4 Hz; ³J(H,H)=3.4 Hz (2H)); 7.84 (tt³J(H,H)=7Hz; ²J(H,H)=1.0 Hz (1H)).

Example 7: Preparation of tris(trichlorosilyl)germanide adduct of BBr₃ (7).

The synthesis of 7 was effected according to Equation 7 from tris(trichlorosilyl)germanide (5) and BBr₃.

[Ph₄P][Ge(SiCl₃)₃]+BBr₃

[Ph₄P][Ge(SiCl₃)₃)₃*BBr₃] Equation 7: Reaction of 5 with BBr₃.

BBr₃ was added at room temperature to a clear yellow solution of 5 in CH₂Cl₂. After 4 days, colourless crystals had precipitated from the yellow reaction solution thus obtained. By means of X-ray diffractometry, the crystal structure of 7 could be determined, shown in FIG. 7A. For reasons of clarity, the cation [Ph₄P]⁺ is not depicted here.

The ²⁹Si-NMR spectrum of 7 is shown in FIG. 7B.

All results of a ¹¹B- and ²⁹Si-NMR spectroscopic investigation ²⁹Si-NMR (99.4 MHz, CD₂Cl₂, 298 K): δ=12.3.

¹¹B-NMR (160.5 MHz; CD₂Cl₂; 298 K): δ=−17.5. 

1-2. (canceled)
 3. A tris(trichlorosilyl)germanide of formula (II): [R₄N]/[R₄P][Ge(SiCl₃)₃]  (II), wherein R=Me, Et, iPr, nBu, or Ph.
 4. A method for preparing the tris(trichlorosilyl)germanide of formula (II) according to claim 3, the method comprising: dissolving GeCl₄ with hexachlorodisilane in a solvent; and reacting in the presence of a stoichiometric amount of [R₄N]/[R₄P]Cl at a temperature of 5 to 40° C.
 5. A tris(trichlorosilyl)germanide adduct of GaCl₃ of formula (III): [Ph₄P][Ge(SiCl₃)₃*GaCl₃]  (III).
 6. A method for preparing the tris(trichlorosilyl)germanide adduct according to claim 5, the method comprising: mixing a tris(trichlorosilyl)germanide of formula (II): [R₄P][Ge(SiCl₃)₃]  (II), wherein R=Ph, with GaCl₃, to obtain a mixture; dissolving the mixture in dichloromethane with stirring; and obtaining the tris(trichlorosilyl)germanide adduct at a temperature of 5 to 40° C. over a period of 1 to 24 hours.
 7. A tris(trichlorosilyl)germanide adduct of BBr₃ of formula (IV): [Ph₄P][Ge(SiCl₃)₃*BBr₃]  (IV).
 8. A method for preparing the tris(trichlorosilyl)germanide adduct according to claim 7, the method comprising: mixing tris(trichlorosilyl)germanide of formula (II): [R₄P][Ge(SiCl₃)₃]  (II), wherein R=Ph, with BBr₃, to obtain a mixture; dissolving the resulting mixture in dichloromethane with stirring; and Obtaining the tris(trichlorosilyl)germanide adduct at a temperature of 5 to 40° C. over a period of 1 to 120 hours. 